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The Effect of a Surface Barrier on Uptake Rates of Dye into Wool Fibers

J.A. Medley

C.S.I.R.O. Wool Textile Research Laboratories, Ryde, N.S.W., Australia

M.W. Andrews

C.S.I.R.O. Wool Textile Research Laboratories, Ryde, N.S.W., Australia

It is shown that any surface barrier to the entry of a dye into a fiber must modify the form of the uptake-time relation, the barrier exerting its greatest influence in the early stages of sorption, but becoming progressively less important as sorption proceeds. This is manifested by an initially concave-upwards tendency in the uptake-timel curve. The analysis, which takes account of variable diffusion characteristics of fibers forming the ~asemhly, is applied to the uptake of Naphthalene Orange G by wool, and a small but definite effect is found, which could for instance be attributed to the epicuticle.

Textile Research Journal, Vol. 29, No. 5, 398-403 (1959)
DOI: 10.1177/004051755902900505


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J.A. Medley and M.W. Andrews
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Textile Research Journal, November 1, 1960; 30(11): 855 - 860.
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J.H. Bradbury
The Amino Acid Analysis of Cuticle-Rich Material from Wool
Textile Research Journal, February 1, 1960; 30(2): 128 - 135.
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