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Textile Research Journal, Vol. 25, No. 7,
592-600 (1955)
DOI: 10.1177/004051755502500703
Density of Modified Cottons Determined with a Gradient Column
Rollin S. Orr
Southern Regional Research Laboratory,1 New Orleans, Louisiana
Louis C. Weiss
Southern Regional Research Laboratory,1 New Orleans, Louisiana
Harry B. Moore
Southern Regional Research Laboratory,1 New Orleans, Louisiana
James N. Grant
Southern Regional Research Laboratory,1 New Orleans, Louisiana
A rapid method which compares favorably in accuracy with that of slower methods for measuring the density of cellulosic materials with a gradient column is described. Densities of several cottons before and after chemical modification by partial acetylation, carboxymethylation, aminization, and mercerization are given. Per cent acetyl can be expressed as a function of density in a linear empirical equation over a range of 13 to 42% acetyl with a precision of ± 2%. Density measurements of decrystallized, ball-mill ground, and acid hydrolyzed cottons were in agreement with the generally accepted con cept of the crystalline-amorphous cellulose phase composition in these materials. Cotton from which water was removed by solvent exchange was found to have a high density before, and a low density after, air drying.

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